Coal desulfurization has come a long way in the past 15 years, and chemical desulfurization has been at the forefront of this progression. Unfortunately, unless some new technique is developed, the chemical desulfurization processes appears to be at a stalemate. ... The Meyers process of removing pyritic sulfur from coal chemically before it ...
WhatsApp: +86 18203695377The flue gas desulfurization process in coalfired power plants is energy and resourceintensive but the ecoefficiency of this process has scarcely been considered. Given the fluctuating unit load and complex desulfurization mechanism, optimizing the desulfurization system based on the traditional mechanistic model poses a great challenge. In this regard, the present study optimized the eco ...
WhatsApp: +86 18203695377The main factor for the results above was that the desulfurization mechanisms were different. Therefore, the research of different desulfurization mechanisms is the main direction of future work. The consequence of this paper would provide data support for the selection of the desulfurization method for high sulfur coal.
WhatsApp: +86 18203695377Mechanism of Pyrite Microbial Desulfurization. The oxidation process of coal conversion is possible by microorganisms after getting influenced by the polyfunctional coal structure and this process usually depends on two main factors: size or shape of coal and surface properties of microorganisms (Konishi et al. 1990). The morphology and ...
WhatsApp: +86 18203695377Wet Desulfurization Technology (WFGD) is the main process for flue gas desulfurization in coalfired power plants in China, mainly including limestonegypsum wet method and seawater desulfurization. At the end of 2014, more than % of the desulfurization equipment was WFGD.
WhatsApp: +86 18203695377During the desulfurization process of coalfired power plants, there are many related parameters that affect the desulfurization efficiency. So it is very difficult to measure the desulfurization efficiency directly. In this paper, in order to reflect the relationship between monitoring process parameters and desulfurization efficiency better, a novel prediction model of desulfurization ...
WhatsApp: +86 18203695377environment, the desulfurization and denitration of flue gas in the combustion process of coal has become an important step. T his work summarizes the desulfur ization and denitration
WhatsApp: +86 18203695377This work was conducted through field tests on a coalfired circulating fluidized bed boiler with a condensation scrubber (CS) for flue gas waste heat recovery installed behind the wet flue gas desulfurization (WFGD) scrubber. Levels of multiple pollutants were investigated along the various flue gas devices of the boiler, with the CS being the ...
WhatsApp: +86 18203695377As a typical industrial byproduct during the flue gas desulfurization process of coalfired, flue gas desulfurization ash (FGDA) with alkali mineral can facilitate the water damage resistance of asphalt mixtures. However, low density and high hydrophilic coefficient of FGDA limit its improvement effect. Hence, the comprehensive moisture ...
WhatsApp: +86 18203695377Abstract To explore the feasibility of organic sulfur removal using organic acids, oxalic acid, citric acid and ascorbic acid were selected as desulfurization reagents. Combined with microwave irradiation technology, desulfurization experiments of highsulfur coal treated with nitric acid were conducted. The orthogonal experimental results showed that the microwave synergistic citric acid ...
WhatsApp: +86 18203695377For future approaches, as well as desulfurization process, increasing the purity of coal may also promote the value of coal and prevent environment pollution. In the study of Etemadifar et al., growing and resting cells of heterotrophic Rhodococcus erythropolis strains PD1, R1, and FMF, and R. qingshengii were utilized in sulfur removal and ...
WhatsApp: +86 18203695377The combined effect of desulfurization and ash removal in the process of coal desulfurization by microwave with peroxyacetic acid was determined by evaluating variations in minerals and sulfur forms using Xray diffraction and Xray photoelectron spectroscopy. Dielectric properties of minerals or organic sulfur functional groups in coal were studied utilizing a vector network analyzer in the ...
WhatsApp: +86 18203695377The limestone gypsumbased wet desulfurization (WFGD) process is widely applied for flue gas desulfurization in coalfired power plants. However, enrichment of elemental chlorine in the desulfurization slurry would significantly impact the desulfurization efficiency, which requires regular discharge of desulfurization wastewater (He and Qi 2010).
WhatsApp: +86 18203695377The coal hydrogen production process requires hightemperature steam as a reactant. Coalfired boilers are usually used to provide hightemperature steam. The ammoniabased desulphurization process is an effective technology to remove SO2 in the coalfired flue gas. However, the mass transfer coefficient of SO2 in such an engineered process is not readily available in the literature. In this ...
WhatsApp: +86 18203695377In addition, the sulfur content of the raw coal reduces from % to %, total desulfurization rate of %, whose organic sulfur desulfurization is % after coal in shake flask experiments. And the desulfurization rate approaches the maximum value on the tenth day (from Figure 2B). It was demonstrated that strain SX12 could ...
WhatsApp: +86 18203695377A large amount of SOx will be produced in the combustion process of coal without desulfurization, which is the main factor causing air pollution, environmental damage and increase.
WhatsApp: +86 18203695377A process for coal desulfurization generates extremely low amounts of heat from microwave energy to induce thermochemical, insitu, reactions to liberate sulfur in the form of stable gaseous species, such as H/sub 2/S, COS and SO/sub 2/. Inventors:
WhatsApp: +86 18203695377Sulfur dioxide is the most important precursor of acid rain and one of the major contaminants generated from coalfired power plants. Currently, the limestonegypsum wet fluegas desulfurization (WFGD) system is the most widely used method for removal of SO 2 from powerplant exhaust fumes. However, the gypsum byproduct of limestonegypsum WFGD ...
WhatsApp: +86 18203695377In addition, the photocatalytic desulfurization process has little effect on the heat value of coal. On a basis of TGDSCDDSC analysis, it is found that the calorific value of the coal after photocatalytic desulfurization was slightly changed and the low temperature oxidation tendency was decreased which is helpful for desulfurized coal storage.
WhatsApp: +86 18203695377The present work describes the desulfurization of coal using mildly reductive method. Both a Yanzhou and a Yanshan coal (referred to as YZ and YS coal, respectively), were treated in an aqueous media employing sodium borohydride (NaBH 4) as reducing agent, which is a well known hydrogen variables investigated include concentration of reductant, time, pH of initial media ...
WhatsApp: +86 18203695377To solve the safety problem of spontaneous combustion of highsulfur coal, applied microbiology, physical chemistry, reaction kinetics theory, combined with the SEM, FTIR and TGDTGDSC experiments and analysis of testing methods, the microbial desulfurization experiments were carried out, and the change law of the desulfurization reaction of coal before and after the element composition, main ...
WhatsApp: +86 18203695377Before and after the desulfurization process; total sulfur, pyritic sulfur, carbon content and calorific value were measured. The highest removal efficiencies of total sulfur and pyritic sulfur for Burdur coal obtained as 41% and 67%, for Tunçbilek coal obtained as 41% and 35%, and for Ermenek coal obtained as 47% and 41%, respectively.
WhatsApp: +86 18203695377The major coal desulphurization technologies prior to combustion are physical coal cleaning, chemical and biological methods. Each has some technical and economical limitations. Physical coal cleaning can only remove limited amount of inorganic sulphur due to insufficient liberation.
WhatsApp: +86 18203695377The FGD products are included in coal combustion products. The components of CCP's are as follows: fly ash, 57 percent; FGD products, 24 percent; bottom ash, 16 percent; and boiler slag, 3 percent. What is flue gas desulfurization? Flue gas desulfurization is a chemical process to remove sulfur oxides from the flue gas at coalburning powerplants.
WhatsApp: +86 18203695377Fluegas desulfurization (FGD) material is a product of a process typically used for reducing SO 2 emissions from the exhaust gas system of a coalfired boiler. The physical nature of these materials varies from a wet sludge to a dry, powdered material depending on the process.
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